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铋和磷元素对Sn-Zn-RE电子微连接钎料组织与性能的影响
杜长华1, 尹立孟2, 苏鉴1, 陈方1, 赵海建1
1.重庆理工大学材料科学与工程学院, 重庆 400054;2.重庆科技学院冶金与材料工程学院, 重庆 401331
摘要:
制备了含不同Bi,P元素的(Sn-9Zn0.05Ce)xBi和(Sn-9Zn0.05Ce)xP钎料合金,观察并分析了钎料的显微组织形貌,测试了钎料的抗拉强度、断后伸长率以及维氏硬度.结果表明,添加Bi元素能显著提高Sn-9Zn0.05Ce钎料合金的抗拉强度和硬度,但同时会明显降低其断后伸长率,而添加微量P元素对钎料的抗拉强度与硬度没有明显的影响.此外,添加Bi和P元素均能促使钎料析出针状或颗粒状富锌相,富锌相随Bi或P元素添加量的增加而增多,并因此影响钎料合金的力学性能.
关键词:  锡-锌钎料  显微组织  抗拉强度  硬度
DOI:
分类号:
基金项目:重庆市重点自然科学基金资助项目(2006BA4034);重庆科技学院校内科研基金项目(CK2010B23)
Influence of Bi and P additions on microstructure and mechanical properties of Sn-Zn-RE solder
DU Changhua1, YIN Limeng2, SU Jian1, CHEN Fang1, ZHAO Haijian1
1.School of Materials Science and Engineering, Chongqing University of Technology, Chongqing 400054, China;2.School of Metallurgy and Materials, Chongqing Institute of Science and Technology, Chongqing 401331, China
Abstract:
The Sn-9Zn0.05Ce lead-free solder with Bi and P additions were prepared, and microstructure, tensile strength, elongation and Vickers hardness of the lead-free solders were studied. Experimental results show that the tensile strength and hardness increase with more Bi addition in Sn-9Zn0.05Ce lead-free solder, while the elongation decreases with Bi addition. P addition in Sn-9Zn0.05Ce lead-free solder does not obviously affect the tensile strength and hardness. In addition, either Bi or P addition in Sn-9Zn0.05Ce lead-free solder would make Zn separate out from Sn-9Zn0.05Ce lead-free solder more easily, and needle-like or grain-like Zn-rich phase can be found in the solder. Moreover, Zn-rich phase increases with more Bi or P additions in the solder, and accordingly has a great effect on the mechanical properties of Sn-9Zn0.05Ce solder.
Key words:  Sn-Zn0.05Ce solder  microstructure  tensile strength  hardness